期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 13, 页码 2708-2714出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201640
关键词
Asymmetric catalysis; Enantioselectivity; Allylic compounds; Iridium
资金
- Pu Jiang Program of Shanghai
- National Natural Science Foundation of China (NSFC) [21272175]
Chiral allylic thioesters were synthesized through a direct iridium-catalyzed asymmetric allylation of KSAc in the presence of KOAc. This strategy provided branched allylic thioesters in good yields with the high levels of enantioselectivity.
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