期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 20, 页码 4219-4222出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300220
关键词
Palladium; Alkynes; Ketones; Ring opening; Annulation; Synthetic methods
资金
- Grants-in-Aid for Scientific Research [25410054] Funding Source: KAKEN
N-Heterocyclic carbene-palladium catalysts are used to promote addition/ring opening of cyclopropenones with terminal alkynes. The ring-opening alkynylation affords alkenyl alkynyl ketones in good yields. For reactions with propargylic esters having an aryl or alkenyl substituent at the propargylic position, [3+2] annulation occurs exclusively to give 4-methylenecyclopentenones.
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