期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2013, 期 20, 页码 4245-4248出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201300545
关键词
Synthetic methods; Dehydrogenation; Cross-coupling; Phosphonation; Silver
资金
- National Natural Science Foundation of China (NSFC) [21074054, 51173078, 21172106]
- National Basic Research Program of China [2010CB923303]
A highly efficient, Ag-I/K2S2O8-mediated regioselective phosphonation reaction has been developed by using electron-deficient directing groups. These phosphonation reactions were performed with N,N-dialkylbenzamides, N,N-dialkylbenzenesulfonamides, and nitrobenzene. This method has a broad substrate scope and offers facile construction of C-P bonds.
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