期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 10, 页码 1994-2000出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101784
关键词
Heterocycles; Amides; Oxidation; Rearrangement
资金
- Important National Science & Technology Specific Projects, China [2009ZX09301-14-1]
- National Natural Science Foundation of China [21102107]
- China Postdoctoral Science Foundation [20110491199]
A simple and efficient method for the synthesis of 1,3-disubstituted ureas and carbamates from amides by using iodosylbenzene as the oxidant is described. Symmetric and asymmetric ureas and carbamates can be prepared by this procedure in up to 98?% yield. Ureidopeptides can also be prepared in good yield by this method.
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