4.5 Article

Cavity-Extended Pillar[5]arenes: Syntheses and Host-Guest Complexation with Paraquat and Bispyridinium Derivatives

期刊

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 30, 页码 5902-5907

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201201003

关键词

Host-guest systems; Pillar-arenes; Pseudorotaxanes; Macrocycles; Supramolecular chemistry

资金

  1. National Natural Science Foundation of China [20834004, 91027006, 21125417]
  2. Fundamental Research Funds for the Central Universities [2012QNA3013]
  3. Program for New Century Excellent Talents in University
  4. Zhejiang Provincial Natural Science Foundation of China [R4100009]

向作者/读者索取更多资源

Cavity-extended pillar[5]arenes containing electron-rich naphthyl groups have been demonstrated to have enhanced binding affinity to linear guests containing electron-deficient pyridinium units. The importance of size effect, charge density, cooperative effect, and C-H...pi interactions were investigated, and these factors play significant roles in the complexation of these hostguest systems.

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