期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 9, 页码 1835-1842出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101718
关键词
Asymmetric synthesis; Total synthesis; Alkaloids; Nitrogen heterocycles; Lactams
资金
- Spanish Ministry of Science and Innovation (MICINN) [CTQ2009-07021/BQU]
- Agencia de Gestio d'Ajuts Universitaris i de Recerca (AGAUR), Generalitat de Catalunya [2009-SGR-1111]
Cyclocondensation reactions between a variety of 2-acyl-3-indoleacetic acid derivatives and (R)-phenylglycinol were studied. Successful results were obtained from N-alkyl keto acid derivatives. The resulting tetracyclic lactams provide straightforward access to enantiopure 1-substituted tetrahydro-beta-carboline alkaloids.
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