期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 23, 页码 4380-4386出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200531
关键词
Indoles; Pyrroles; Alkynes; Aminopalladation; Palladium catalysis; Cyclization; Solvent effects
资金
- National Nature Science Foundation of China [21032005, 20972137]
By choosing DMF and dioxane as solvent, skeletons of indoles and pyrroles were constructed from alkynes and amines in the presence of PdCl2, respectively. These Pd-catalyzed reactions were phosphane-free with high atom efficiency and could be conducted under mild basic conditions. The proposed mechanism for the selective formation of indoles and pyrroles in different solvents is also discussed in this paper.
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