4.5 Article

Synthesis of 2,6-Bis(oxazolyl)pyridine Ligands for Luminescent LnIII Complexes

期刊

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 21, 页码 3905-3910

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200177

关键词

Dehydroaminobutyric acid; Dipicolinic acid; Bis(oxazoles); Lanthanides; Luminescence

资金

  1. Foundation for Science and Technology (FCT, Portugal)
  2. Quadro de Referencia Estrategico Nacional (QREN)
  3. Fundo Europeu de Desenvolvimento Regional/European Union (FEDER/EU) through research center CQ/UM [PEst-C/QUI/UI0686/2011 (FCOMP-01-0124-FEDER-022716)]
  4. Fundo Europeu de Desenvolvimento Regional/European Union (FEDER/EU) through research center CFUM [PEst-C/FIS/UI0607/2011 (FCOMP-01-0124-FEDER-022711)]
  5. Fundo Europeu de Desenvolvimento Regional/European Union (FEDER/EU) [PTDC/QUI/81238/2006]
  6. FEDER/COMPETE [FCOMP-01-0124-FEDER-007467]
  7. National Programme for Scientific Re-equipment [REDE/1517/RMN/2005]
  8. Programa Operacional Ciencia e Inovacao (POCI) (FEDER)
  9. FCT [SFRH/BD/38766/2007, SFRH/BPD/29112/2006]
  10. Fundação para a Ciência e a Tecnologia [SFRH/BD/38766/2007, 2021.06560.BD, PTDC/QUI/81238/2006] Funding Source: FCT

向作者/读者索取更多资源

New bis(oxazolyl)pyridine ligands for LnIII ions were prepared by using an expeditious methodology from threonine and dipicolinic chloride. The synthetic strategy includes a dehydration step to give a bis(dehydroaminobutyric acid) derivative followed by bromination and cyclization with DBU. Photophysical studies of EuIII and TbIII complexes of these ligands showed that the 2,6-bis(oxazolyl)pyridine moiety acts as an effective sensitizer for lanthanide luminescence and indicate the formation of 3:1 complexes [Ln{bis(oxazole)pyridine}3]3+.

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