期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 28, 页码 5462-5470出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200930
关键词
Cycloaddition; Azides; Alk-ynes; Click chemistry; Silver
资金
- Natural Sciences and Engineering Research Council (NSERC) of Canada
- Cytec Canada, Inc.
- McMaster University
A highly efficient, chemically stable, and well-defined homogeneous silver(I) catalyst is reported for the cycloaddition of azides onto terminal alkynes (Ag-AAC reaction). The Ag-AAC reaction occurs at room temperature or with heating to deliver exclusively the corresponding 1,4-triazole. A pronounced ligand effect was discovered through systematic modification to the ligand structure resulting in the discovery of a chemically stable active catalyst for this reaction.
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