4.5 Article

Efficient Method for Varying the Anions in Quaternary Onium Halides

期刊

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 19, 页码 3566-3569

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201200370

关键词

Ion exchange; Ionic liquids; Anions; Green chemistry

资金

  1. Fundamental R&D Program for Integrated Technology of Industrial Materials
  2. Ministry of Knowledge Economy
  3. Inter-Metropolitan Cooperation Development
  4. Presidential Committee on Regional Development of Korea

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Quaternary onium salts of halides can be efficiently converted into the corresponding quaternary onium salts of various anions [NO3, BF4, PF6, CF3SO3, CH3SO3, ClO4, p-CH3C6H4SO3, CF3CO2, 2,4-(NO2)2C6H3O] by treating the onium halide with trimethyl phosphate under neat condition in the presence of an equivalent amount of conjugate acid of the desired anion.

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