期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 5, 页码 831-841出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001558
关键词
Fluorine; Silicon; Amines; Schiff bases; Nucleophilic trifluoromethylation
资金
- Russian Foundation for Basic Research [08-03-00428]
- Russian Academy of Sciences [7]
- Ministry of Science [02.740.11.0258]
The review covers nucleophilic addition reactions of the CF3 carbanion to C=N bonds. Trifluoromethylation reactions of imines, nitrones, hydrazones, iminium ions and azomethine ylides are discussed. Various trifluorometylating reagents are considered, among which the major emphasis is placed on reactions using the Ruppert-Prakash reagent.
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