期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 1, 页码 29-42出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201100921
关键词
Steroids; Synthetic methods; Synthesis design; Asymmetric synthesis; Transition metals
资金
- Ministry of Education, Youth and Sports of the Czech Republic [1M0508, MSM0021620857]
This short review aims to summarize recent advances in the use of transition-metal-catalyzed and -mediated methodology for the synthesis of steroid and steroid-like skeletons reported in the last decade. The methodologies used include transition-metal-catalyzed or -mediated [2+2+2] and other cycloadditions, the Pauson-Khand reaction, cross-coupling and Heck reactions, processes based on the activation of single and multiple bonds, metathesis reactions, hydrovinylation, and other reactions. Several examples of total syntheses of steroid compounds [e.g., (+)- and (-)-estrone, desogestrel] by these procedures are presented.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据