期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 13, 页码 2519-2523出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001729
关键词
Boron; Biaryls; Copper; C-C coupling; Homogeneous catalysis
资金
- National Natural Science Foundation of China [21021001, 21072134]
- Program for Changjiang Scholars and Innovative Research Team in University [IRT0846]
Homocoupling of arylboronic acids has been successfully carried out by using the inexpensive simple copper salt CuCl as the catalyst in methanol to obtain symmetric biaryls in good to excellent yields. The reaction proceeds with a CuCl loading of 2 mol-% under extremely mild conditions: in air, at room temperature, without the need of any additives such as base, oxidant, or ligand.
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