期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 36, 页码 7400-7406出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101016
关键词
Synthetic methods; Reduction; Esters; Siloxanes; Molybdenum; Vana-dium
资金
- Fond Unique Inter-ministeriel (REDSUP)
An efficient reduction of aromatic and aliphatic esters with 1,1,3,3-tetramethyldisiloxane in combination with [MoO2(acac)2] or [V(O)(OiPr)3] is reported. In the former system, the presence of triphenylphosphane oxide allows high conversion and good isolated yield to be reached. For the latter system, no ligand is necessary to obtain the corresponding alcohols with similar results.
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