期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 10, 页码 1914-1921出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001432
关键词
Calixarenes; Hydrogen bonds; N ligands; Macrocycles; Aromatic substitution; Spectrophotometry
资金
- Centre National de la Recherche Scientifique
- Ministere de la Recherche et des Nouvelles Technologies
- Agence Universitaire de la Francophonie
We describe the synthesis and spectrophotometric studies of novel N(H)-azacalix[4]arenes. The unprecedented direct functionalization of the N(H) bridges furnished N(R)-bridged aza[1(4)]calixarene 11 that could complex a neutral guest (CH2Cl2) or could be further reduced into corresponding tetraamino derivative 12.
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