期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2012, 期 2, 页码 409-416出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201101346
关键词
Ketotriazoles; Diketotriazoles; Copper; Oxidation; Synthesis design
资金
- Ministere de l'Enseignement et de la Recherche Scientifique
The catalytic oxidation of alpha-ketotriazoles to alpha,beta-diketotriazoles was performed with CuCl2 or CuI/2,9-dimethyl-1,10-phenanthroline in air at 80 degrees C in good yields. Studies showed that the triazole group participates in complexation to the copper and favors oxidation.
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