期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 3, 页码 607-613出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001274
关键词
Cycloaddition; Azomethine ylides; Aldehydes; Amino alcohols
资金
- Knut and Alice Wallenberg Foundation
- Swedish Research Council
- Estonian Science Foundation [7260, 7808]
- Estonian Targeted Financing Grant [TLOTI0073]
A 1,3-dipolar cycloaddition reaction of azomethine ylides to aldehydes is described. The azomethine ylides, generated by thermal electrocyclic ring opening of aziridines, adds to aldehydes in good yields with moderate to good selectivities to furnish oxazolidines. The oxazolidines were subsequently hydrolyzed to the corresponding amino alcohols, giving the anti diastereomer as the major product.
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