4.5 Article

Copper-Catalyzed Direct Synthesis of Di- and Triphenylamines: A Dramatic Accelerating Effect of 2-Aminophenols

期刊

EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 36, 页码 6967-6973

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001113

关键词

Copper; Amines; Amino alcohols; N,O ligands; Reaction mechanisms

资金

  1. National Natural Science Fundation of China [20876021]
  2. Education Department of Liaoning Province [2009S021]

向作者/读者索取更多资源

Utilizing the dramatic accelerating effect of 2-aminophenols, we developed a copper-catalyzed system for the selective synthesis of di- and triphenylamines. In addition, N- and O-arylation could be achieved in coupling reactions between 2-aminophenol and nitroaryl halides.

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