期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 21, 页码 4145-4150出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000427
关键词
Carbenoids; Carbocations; Rearrangement; Spiro compounds
资金
- Russian Foundation for Basic Research [09-03-00717-a]
The series of 2-phenyl- and 2,2-diphenyl gem-dihalogenospiropentanes were employed as model compounds to study the carbenoid rearrangement with the use of methyllithium. The scope and limitations of this skeletal rearrangement are outlined and its mechanism is discussed.
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