期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 2, 页码 271-279出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000936
关键词
Pyridine N-oxides; Boekelheide rearrangement; Cyclization; Intramolecular reactions; Nitrogen heterocycles; Synthetic methods
资金
- GlaxoSmithKline of Verona
Pyrrolidines and piperidines were synthesized from (aminoalkyl)pyridine N-oxides with a general and quite efficient method developed by using di-tert-butylsilyl bis(trifluoromethanesulfonate) as a new promoter for a Boekelheide-type reaction. The use of a new Boekelheide promoter, which is compatible with amino groups, opens new perspectives in view of its application in intramolecular cyclizations.
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