期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 9, 页码 1688-1693出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200901183
关键词
Amines; N ligands; Bifunctional chelating agents; Macrocycles
资金
- Centre National de la Recherche Scientifique (CNRS)
- French Ministry of Research
- Regional Council of Burgundy
- French Ministry for Research
A powerful synthetic route for the preparation of new poly-azamacrocycles, valuable precursors of bifunctional chelating agents with applications in nuclear medicine, is reported. The desired functional group was introduced onto the macro-cycle backbone during the cyclization step, thus avoiding the tedious preparation of a C-functionalized synthon. The regioselective reaction of macrocycles bearing an aminomethyl pendant arm with aldehydes is also described.
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