期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 10, 页码 1849-1853出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200901509
关键词
Organocatalysis; Michael addition; Asymmetric synthesis; Amines
资金
- National Natural Science Foundation of China [20802075]
- Chinese Academy of Sciences
Highly enantioselective Michael addition of acetone to a variety of nitroalkenes promoted by simple chiral primary amine bifunctional catalysts (e.g., Noyori's Ts-DPEN ligand) together with terephthalic acid in excellent yields (84-99%) and enantioselectivities (93-98 % ee) is reported.
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