期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2011, 期 5, 页码 908-911出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201001160
关键词
Copper; Schiff bases; Heterocycles; Amination; Cycloamination
资金
- National Science Foundation (NSF)
- Division Of Chemistry
- Direct For Mathematical & Physical Scien [848591] Funding Source: National Science Foundation
The amino-functionalization of tertiary, secondary and benzylic C-H bonds of tethered carbamates and sulfamates by iodosobenzene is catalyzed by Cu-I-diimine complexes in moderate to good yield. Employing homochiral imine-Cu catalysts affords oxazolidinones and oxathiazinanes with modest enantioselectivity.
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