期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 20, 页码 3945-3955出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000134
关键词
Palladium; Cross-coupling; Bismuth; Oxygen heterocycles; Organometallic reactions
资金
- Department of Science and Technology (DST), New Delhi [SR/S5/GC-11/2008]
- University Grants Commission (UGC), New Delhi
- Council of Scientific and Industrial Research (CSIR), New Delhi
Triarylbismuth compounds have been cross-coupled as atom-efficient multicoupling organometallic nucleophiles with 4-bromo- and 4-(trifluoromethylsulfonyloxy)coumarins under palladium catalysis conditions. These reactions afforded an array of 4-arylcoumarins in high yields. The general palladium protocol has been demonstrated to be efficient for the coupling of both bromide and triflate derivatives of coumarins with triarylbismuth reagents.
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