期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 35, 页码 6810-6819出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201000941
关键词
Carbocycles; Heterocycles; Sulfones; Desulfonylation; Michael addition; Nucleophilic substitution
资金
- Department of Science and Technology (DST), New Delhi
- Council for Scientific and Industrial Research, New Delhi
A powerful, flexible, and stereoselective general strategy for the construction of chirally pure six-membered heterocycles and carbocycles by utilizing a tandem Michael-S(N)2 sequence is described. The strategy avoids the tedious synthesis of separate starting materials prior to cyclization. The expedient and general strategy, which is virtually untapped until now, will enrich the arsenal of synthetic chemists for the preparation of cyclic compounds.
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