期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2010, 期 12, 页码 2314-2323出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200901460
关键词
Boron; Nitrogen heterocycles; Dyes/pigments; Fluorescence; Fluorescent probes; Photophysics; Nucleophilic substitution
资金
- Council of Scientific & Industrial Research (CSIR)
- Department of Science & Technology (DST)
- Indian Institute of Technology, Bombay
Nucleophilic substitution reactions of 2-, 3- and 4-hydroxy-pyridines with 3,5-dibromo meso-aryl and meso-furyl boron-dipyrromethenes (BODIPYs) resulted in the formation of the corresponding 3,5-bis(oxopyridinyl)-BODIPYs and 3,5-bis(pyridinyloxy)-BODIPYs in decent yields. The effect of a pyridone versus an oxypyridine at the 3- and 5-positions on the spectral, electrochemical and photophysical properties were studied as a function of solvent. The 3,5-bis(oxopyridinyl)- BODIPYs exhibit broad, red-shifted absorption and emission bands, decreased quantum yields and lifetimes, displayed large Stokes shifts and easier reductions than did the 3,5-bis(pyridinyloxy)-BODIPYs. The differences in the properties of these two classes of BODIPY dyes are attributed to the extension of pi-delocalization associated with the electron-deficient nature of the pyridone groups.
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