期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2009, 期 3, 页码 403-411出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800991
关键词
Carbohydrates; Glycosides; Regioselectivity; Glycosylation; myo-Inositol; n-Pentenyl orthoester; Thioglycoside; Donor-acceptor systems
资金
- Ministerio de Ciencia y Tecnologia (MCYT) [CTQ-2006-C03]
- US National Science Foundation [CHE-0243436]
The regioselectivity in the glycosylation of myo-inositol orthopentanoate with an n-pentenyl orthoester (NPOE) and an armed thioglycoside as glycosyl donors has been examined. The NPOE displayed higher regioselectivity and its preferred site for glycosidation coincided with that for selective acylation with RCOCl/pyridine. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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