期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2009, 期 11, 页码 1691-1697出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200801269
关键词
Cycloaddition; Fluorescence; Optical switching; Dynamic covalent chemistry
资金
- French Ministere de I'Education Nationale de la Recherche et de la Technologie for a doctoral fellowship
Studies of the Diels-Alder reactions between 9,10-dimethylanthracene and cyano-functionalized dienophiles led to the identification and characterization of new dynamic systems under ambient conditions. Among these dienophiles were tricyanoethynylethylene derivatives, which gave access to reversible thermal switching of fluorescent properties through binding to and release of the dimethylanthracene partner. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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