期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2009, 期 11, 页码 1806-1811出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200900009
关键词
Heterocycles; Alkaloids; Hydroamination; Sulfur
资金
- Universite catholique de Louvain
- Merck Sharp and Dohme
Small amounts of n-butyllithium catalyse the highly efficient hydroamination of a large variety of vinyl sulfides. This novel methodology offers an easy access to a wide range of nitrogen heterocycles, including simple pyrrolidines and piperidines, as well as more complex bicyclic compounds. Subsequent transformations of the sulfur group led to the formation of functionalised alkaloid-like substructures. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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