期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2008, 期 32, 页码 5391-5400出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800597
关键词
Nitroxides; Fluorescence; Radicals; Profluorescent probes
资金
- Australian Research Council Centre of Excellence for Free Radical Chemistry and Biotechnology [CEO 0561607]
- Queensland University of Technology
New profluorescent mono- and di-isoindoline nitroxides (5, 11, 16 and 19) containing 9,10-diphenylanthracene and 9,10-bis(phenylethynyl)anthracene structural cores were synthesised by palladium-catalysed Suzuki and Sonogashira couplings. These nitroxide-fluorophore probes possess strongly suppressed fluorescence, even in the presence of only one nitroxide radical. Upon reduction, or reaction with other radicals, normal fluorescence emission is returned. The significant difference in fluorescence output between the nitroxides and their corresponding diamagnetic analogues makes these probes ideal tools for imaging polymer degradation using fluorescence microscopy. ( (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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