期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2008, 期 32, 页码 5379-5382出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200800825
关键词
Chemoselectivity; Domino reaction; Guaianolides; Multicomponent reactions; Natural products
资金
- French research ministry
- Universite Paul Cezanne
- Centre National de la Recherche Scientifique (CNRS [UMR 6263]
A promising synthetic route towards bioactive guaianolide sesquiterpene factories is presented. The strategy is based on a recently invented multicomponent reaction (MARDi cascade) and subsequent highly chemoselective and domino transformations for the expeditious stereoselective preparation of the tricyclic core of the natural products. ( (C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008)
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