期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2008, 期 8, 页码 1331-1335出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.200701052
关键词
fluorine; racemates; amino acids; peptides
variety of fluorine-containing amino acid and dipeptide precursors bearing different lengths of perfluoroalkyl chains were separated into their enantiorners and diastereomers, respectively, by the orthogonal use of fluorous and chiral HPLC columns. These results show the applicability of fluorous racemic mixture synthesis for various fluorinated chiral products without introducing conventional cleavable fluorous tags. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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