期刊
EUROPEAN JOURNAL OF LIPID SCIENCE AND TECHNOLOGY
卷 114, 期 10, 页码 1183-1192出版社
WILEY-BLACKWELL
DOI: 10.1002/ejlt.201200097
关键词
Cardanol; Detergent; Double bond isomerization; Kairomone component; Metathesis
资金
- Royal Society
- Leverhulme Trust under the Leverhulme-Royal Society Africa Award
Synthesis of a tsetse fly kairomone component (3-propylphenol), a detergent [sodium 2-(dec-8-enyl)-6-hydroxybenzenesulfonate], a polymer additive (1-octene), and a detergent precursor [3-(non-8-enyl)phenol] using cardanol [3-(pentadec-8-enyl)phenol], has been accomplished. Both carboncarbon double bond isomerization and metathesis methodologies were employed in the syntheses of these target molecules. The kairomone component was obtained, albeit in low yield, in three steps starting with cardanol. Synthesis of a new detergent, sodium 2-(dec-8-enyl)-6-hydroxybenzenesulfonate, was achieved by direct metathesis of cardanol with cis-2-butene followed by sulfonation and basification. Finally, synthesis of 1-octene and 3-(non-8-enyl)phenol was accomplished in one pot by direct metathesis of cardanol with ethylene. These products have been characterized spectroscopically, especially using 1H and 13C NMR.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据