期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2014, 期 14, 页码 2432-2439出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201402014
关键词
Sensors; Organic pollutant detection; Silver; Nanoparticles; Photochemistry
资金
- National Natural Science Foundation of China (NSFC) [21302176]
- Cultivate Young Talents Foundation of CAEP [QNRC-201206]
- Development Foundation of CAEP [2013B0302042]
Recyclable and sensitive surface-enhanced Raman scattering (SERS) sensors for the detection of a variety of organic pollutants were fabricated from 3D hierarchical ZnO-Ag hybrids, which were synthesized by an efficient and green approach. The ZnO nanostructure could be controlled by applying a facile organic-chemical-assisted hydrothermal method. The obtained structures were then decorated with different-sized Ag nanoparticles (Ag NPs) on their side surfaces and top ends to construct 3D hierarchical ZnO-Ag nanocomposites for use as multifunctional SERS substrates. The obtained SERS sensor manifested a high sensitivity to rhodamine 6G (R6G) at a low concentration of 1x10(-13) M and a detection limit as low as 5x10(-9) M for the organic herbicide 4-chlorophenol (4-CP). Moreover, because of the good, stable photocatalytic properties of this exotic 3D hierarchical structure, the ZnO-Ag hybrids could self-clean under UV irradiation; this allowed repeatable SERS detection of many organic pollutants over more than three cycles with tolerable intensity attenuation. Finally, the unique repeatable detection of the organic dye R6G and the persistent organic pollutant (POP) 2,4-dichlorophenoxyacetic acid (2,4-D) demonstrates a new route to eliminate the single-use problem of traditional SERS substrates and suggests promising applications of such materials as real-time online sensors for organic pollutant detection.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据