期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 30, 页码 5099-5102出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201402685
关键词
C-H activation; Carboranes; Insertion; Silicon; Boron; N ligands; Carbene homologues
资金
- Deutsche Forschungsgemeinschaft (DFG) [TA 75/16-1]
Reaction of donor-stabilized silylene 1 (which is three-coordinate in the solid state and four-coordinate in solution) with 1,2-dicarba-closo-dodecaborane affords neutral six-coordinate silicon(IV) complex 2 with a carboranyl ligand through selective C-cluster-H bond activation. Compound 2 undergoes selective Si-C bond cleavage with acetonitrile to form neutral six-coordinate silicon(IV) complex 3 with a cyanomethyl ligand and 1,2-dicarba-closo-dodecaborane. Compounds 2 and 3 were characterized by crystal structure analyses and multinuclear NMR spectroscopy in the solid state and in solution. In addition, compound 2 was studied by DFT calculations.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据