期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2013, 期 30, 页码 5240-5246出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201300878
关键词
Metallasilsesquioxanes; Oxidation; Homogeneous catalysis; Copper; Structure elucidation
资金
- Russian Foundation for Basic Research [11-03-00646-a, 12-03-00084-a]
A new method of metallasilsesquioxane synthesis is described for the first time. According to this method, a partial nucleophilic cleavage of polymeric copper phenylsilsesquioxane by the use of sym-cis-tetraphenylcyclotetrasiloxanolate nonaethanolate (1) gave previously unknown binuclear cage-like copper silsesquioxane [(PhSiO1.5)(10)(CuO)(2)(NaO0.5)(2)4EtOH] (2). The unprecedented structure of 2, the so called Cooling Tower structure, was confirmed by single-crystal X-ray diffraction analysis. Compound 2 was found to be an excellent catalyst in oxidation reactions of benzene and alcohols with peroxides in acetonitrile solution at 50-70 degrees C.
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