期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 2014, 期 7, 页码 1131-1136出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201301208
关键词
Metathesis; Ruthenium; Homogeneous catalysis; Chelates; Protonation
资金
- National Science Centre (Poland) [UMO-2011/03/B/ST5/01047]
New aryloxybenzylidene ruthenium chelates behave like a promising latent catalyst of olefin metathesis. The catalysts are characterised by substantial stability and catalytic inactivity in their dormant forms and a dramatic increase in activity after addition of a solution of HCl in ether. The mechanism of activation involves protonation of the phenoxide and the formation of a highly catalytically active hydroxybenzylidene ruthenium chelate.
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