期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 2, 页码 228-231出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201200665
关键词
Photochemistry; Sensitizers; Photooxidation; Singlet oxygen; Platinum
资金
- National Natural Science Foundation of China (NSFC) [20972024, 21073028, 21273028]
- Royal Society of Chemistry (RSC), UK
- NSFC China-UK Cost-Share Science Networks [21011130154]
- Science Foundation Ireland (SFI E.T.S. Walton Program) [11/W.1/E2061]
- Fundamental Research Funds for the Central Universities [DUT10ZD212]
- Ministry of Education [NCET-08-0077]
- Dalian University of Technology
Cyclometalated Pt-II complexes that show strong visible-light absorption and long-lived triplet excited states were used as efficient singlet oxygen (O-1(2)) sensitizers for the photooxidation of 1,5-dihydroxynaphthalene (DHN). The photooxidation velocity of the cyclometalated Pt-II complex is 4.4 times that of the conventional Ir-III complex triplet photosensitizers that do not show strong absorption of visible light.
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