期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 3, 页码 412-429出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201100880
关键词
Cooperative catalysis; Pincer complexes; N ligands; Homogeneous catalysis; C-H activation
资金
- Deuthsche Forschungsgemeinschaft [SCHN950/2-1]
- IDK Nanocat
- TUM graduate school
In this review, the coordination chemistry of electron-rich metal complexes with the simple aliphatic, anionic diphosphanylamido ligand {N(CH2CH2PR2)(2)}(-) is covered and compared with other commonly used, anionic PEP (E = C, N) pincer ligands. The strong pi-basicity of this ligand enables both the stabilization of electronically and coordinatively highly unsaturated complexes and their use as cooperating ligands in bifunctional stoichiometric bond activation reactions and catalysis. Versatile ligand backbone dehydrogenation gives access to related enamido and dienamido ligands {(R2PCHCH)N(CH2CH2PR2)}(-) and {N(CHCHPR2)(2)}(-), respectively. This oxidative functionalization enables fine-tuning of the ligand donor properties and thereby of the structural features, electronic structure, and reactivity of the respective complexes, which is discussed for several examples.
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