期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 5, 页码 613-625出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201001184
关键词
C-F activation; Fluoroorganics; Fluorine; Rhodium; Homogeneous catalysis
资金
- Deutsche Forschungsgemeinschaft (DFG)
- Fonds der Chemischen Industrie
- Berlin DFG
Rhodium complexes are excellent tools for the activation of aromatic and olefinic carbon-fluorine bonds. C-F bond cleavage reactions are key steps for the derivatization of highly fluorinated compounds via stoichiometric or catalytic reaction pathways. The reaction routes involve hydrodefluorinations, but also the selective introduction of functional groups at distinctive positions, to provide access to new fluorinated building blocks. One can identify two general types of rhodium precursors that can induce the C-F activation step. Cyclopentadienyl compounds have been applied for thermal and photochemical C-F bond cleavage reactions of aromatics in solution, but oxidative addition steps have also been investigated in matrix isolation studies at low temperature. Square-planar hydrido, silyl, and boryl complexes are often involved in unique stoichiometric and catalytic processes for the derivatization of aromatics and olefins.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据