期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 16, 页码 2819-2827出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201101099
关键词
Metal-organic frameworks; -Vanadium; Oxidation; Heterogeneous -catalysis
资金
- Ghent University (BOF)
- Flemish Government [01M00409]
- Ghent University, GOA [01G00710]
- European Research Council (ERC) [240483]
A vanadium 2,6-naphthalenedicarboxylate, VIII(OH)(O2CC10H6CO2)center dot H2O, denoted as COMOC-3as (COMOC = Center for Ordered Materials, Organometallics and Catalysis, Ghent University), has been synthesized under hydrothermal conditions by means of both a solvothermal and a microwave synthesis procedure. The structure shows the topology of an aluminium 2,6-naphthalenedicarboxylate, the so-called MIL-69 (MIL = Materials of the Institute Lavoisier). After calcination at 250 degrees C in air, the VIII center was oxidized to VIV with the structure of VIVO(O2CC10H6CO2) (COMOC-3). The oxidation process was verified by cyclic voltammetry and EPR spectroscopy. The crystallinity was investigated by variable-temperature XRD. The title compound is stable against air and moisture. The catalytic performance of COMOC-3 was examined in the liquid-phase oxidation of cyclohexene. COMOC-3 exhibited similar catalytic performance to MIL-47 [VO(O2CC6H4CO2)]. The compound is reusable and maintains its catalytic activity through several runs.
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