期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 11, 页码 1604-1607出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200901182
关键词
Carbene ligands; Cycloaddition; Rhodium; Ligand design; Isomers
资金
- Engineering and Physical Sciences Research Council (EPSRC) [EP/C528638/1, EP/C53090X/1, GR/S86105/01, GR/R06458/01]
- National Crystallography Service
- Science and Technology Facilities Council (STFC)
- Engineering and Physical Sciences Research Council [EP/C53090X/1] Funding Source: researchfish
An unsaturated seven-membered amidinium salt 7 decomposes in the presence of metal salts under basic conditions. However, 7 readily forms a Diels-Alder cycloadduct with CpH from which the Rh-I complexes may be prepared. Thus, structurally elaborate, sterically crowded carbene ligand complexes bearing peripheral unsaturated functionality are available in a short versatile synthesis.
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