期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 22, 页码 3423-3428出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.201000558
关键词
Alkaline earth metals; Cations; Anions; Ring-opening polymerization; Lactides
资金
- Centre National de la Recherche Scientifique (CNRS)
- Institut Universitaire de France (IUF)
- Total Petrochemicals
Well-defined, base free cations of zinc and the alkaline-earth metals (Mg, Ca, Sr, Ba) supported by a multidentate phenolate ligand and stabilized by perfluorinated weakly coordinating counterions are readily available by simple procedures; the solid-state structures of the magnesium and calcium derivatives were elucidated. Upon treatment with an excess of iPrOH, these complexes generate highly efficient binary catalytic systems for the immortal ring-opening polymerization of L-lactide, yielding poly(L-lactide)s with controlled architectures and molecular features.
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