期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 9, 页码 1137-1144出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200800944
关键词
Carbenes; Cyclopropanation; Diastereoselectivity; Olefins; Transition metals
资金
- Ministerio de Educacion [CTQ2008-00042BQU]
- Junta de Andalucia [P05-FQM-0914, P07-FQM-02870]
The control of the cis/trans diastereoselectivity by catalyst design in the olefin cyclopropanation reaction with ethyl diazoacetate is reviewed. Catalysts based on ruthenium, copper, rhodium, iron, osmium. and cobalt are discussed. The degree of stereocontrol achieved for styrene and related aryl-containing olefins is higher than that for terminal alkenes with no aryl substituents. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2009)
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