期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 5, 页码 655-672出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200701051
关键词
antiaromaticity; fluorine heteroatom chemistry; sulfur-nitrogen heterocycles; molecular structures; persistent radicals; reactivity synthesis
This review highlights the most important advances in the heteroatom chemistry of 1,3,2,4-benzodithiadiazines (pi-excessive and formally antiaromatic heterocycles), covering methods for synthesis, nontrivial features of the molecular and pi-electronic structure, spectral properties, and reactivity, in particular the transformations into persistent pi-radicals. The chemistry of 1,3,2,4-benzodithiadiazines is compared to that of related chalcogen-nitrogen compounds, both cyclic and acyclic. ((c) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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