期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 1, 页码 44-47出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200700929
关键词
ruthenium; solid-state structure; self-assembly; Pi interactions; optical properties
A unique supramolecular network of the trimetallic building unit [(bPY)(2)Ru(LO)Na(LO)Ru(bpy)(2)](ClO4)(5)center dot 3H(2)O {bpy = 2,2'-bipyridine, LO = 7-methoxy-5-(4-methoxyphenyl)-2,3-bis-(4-methoxyphenylimino)-3,5-dihydro-2H-phenazin-1-one} is described. Crystal growth is driven by several synergistic intermolecular interactions including ClO4-pi, pi-pi, C-H center dot center dot center dot pi and hydrogen bonding. Optical properties of the supramolecule are modified due to aggregation. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
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