期刊
EUROPEAN JOURNAL OF INORGANIC CHEMISTRY
卷 -, 期 20, 页码 3177-3185出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejic.200701308
关键词
CO2 fixation; zinc oxide; precursor chemistry; carbamate complexes
Herein we report on CO2 fixation by insertion into the ZnN bonds of the two molecular compounds EtZnN(iPr)(2) and EtZnN(iBU)(2). The tetrameric carbamate complexes [EtZn-(O2CNR2)](4) (R = iPr and iBu) were found to be the products of these reactions. The structures of the complexes were established by single-crystal X-ray diffraction. Thermal decomposition of the carbamate complexes was studied by applying a variety of different analytical techniques. These studies show that the compounds are suitable precursors for nanosized ZnO particles of ca. 10 nm diameter synthesised under mild conditions (< 200 degrees C) with the oxygen atoms originating from the reactant CO2. ((C) Wiley-VCH Verlag GmbH & Co. KGaA, 69451 Weinheim, Germany, 2008).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据