期刊
EPL
卷 99, 期 3, 页码 -出版社
EPL ASSOCIATION, EUROPEAN PHYSICAL SOCIETY
DOI: 10.1209/0295-5075/99/37008
关键词
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资金
- EU commission
- Conseil regional de Bretagne
- Universite Europeenne de Bretagne
- Agence Nationale de la Recherche [ANR 2011 BS09 002]
We report the working expressions of calculation of local dielectric permittivity (epsilon(r)) under nanoconfinement from dipolar spatial correlations. Three confined geometries are investigated: planar, cylindrical and spherical interfaces. We apply these relations to the calculation of the local components of epsilon(r) of water confined in a porous silica framework. Microscopically we highlight that the dielectric profile is correlated to the density of water and hydrogen bonding network. Copyright (C) EPLA, 2012
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