期刊
JOURNAL OF SEPARATION SCIENCE
卷 38, 期 9, 页码 1577-1583出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/jssc.201401373
关键词
2,3-Diaminonaphthalene; Dispersive liquid-liquid microextraction; Selenium; Tea
资金
- National Natural Science Foundation of China [21377167]
- Science Foundation of China University of Petroleum, Beijing [KYJJ2012-01-15]
Selenium is an important element for human health, and it is present in many natural drinks and foods. Present study described a new method using dispersive liquid-liquid microextraction prior to high-performance liquid chromatography with a UV variable wavelength detector for the determination of the total selenium, Se(IV), Se(VI), and total organoselenium in tea samples. In the procedure, 2,3-diaminonaphthalene was used as the chelating reagent, 400 mu L acetonitrile was used as the disperser solvent and 60 mu L chlorobenzene was used as the extraction solvent. The complex of Se(IV) and 2,3-diaminonaphthalene in the final extracted phase was analyzed by high-performance liquid chromatography. The factors influencing the derivatization and microextraction were investigated. Under the optimal conditions, the limit of detection was 0.11 mu g/L for Se(IV) and the linearity range was in the range of 0.5-40 mu g/L. This method was successfully applied to the determination of selenium in four tea samples with spiked recoveries ranging from 91.3 to 100%.
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