期刊
ENVIRONMENTAL TECHNOLOGY
卷 34, 期 10, 页码 1307-1317出版社
TAYLOR & FRANCIS LTD
DOI: 10.1080/09593330.2012.746734
关键词
Li-ion battery; adsorption; recovery; solvent impregnated resins; PC-88A; Cyanex 272
资金
- Ministry of Environment of Japan [K2127, K22091, K2340]
- Grants-in-Aid for Scientific Research [23360344, 24656476] Funding Source: KAKEN
Selective recovery of valuable metals (Cu2+, Co2+ and Li+) from leachate of spent lithium-ion (Li-ion) batteries was investigated in acidic chloride media using solvent impregnated resins (SIRs). An SIR containing bis(2-ethylhexyl) phosphoric acid (D2EHPA) had high selectivity for Fe3+ and Al3+, with an order of selectivity Fe3+ > Al3+ > Cu2+ > Co2+. Fe3+ and Al3+ could be removed from synthetic leachate by precipitation, followed by column adsorption with the SIR containing D2EHPA. The synthetic leachate was then applied to chromatography for selective recovery of Cu2+, Co2+ and Li+. The solution was first fed upward to a column packed with an SIR containing 2-ethylhexylphosphonic acid mono-2-ethylhexyl ester (PC-88A) for selective separation of Cu2+, followed by upward feed to another column packed with an SIR comprising PC-88A and bis(2,4,4-trimethylpentyl) phosphinic acid (Cyanex 272) for selective recovery of Co2+. Finally, a column packed with a synergistic SIR containing both 1-phenyl-1,3-tetradecanedione (C(11)phDK) and tri-n-octylphosphine oxide (TOPO) was used for selective recovery of Li+. A process flowsheet is proposed for selective recovery of Cu2+, Co2+ and Li+ using several SIRs. This process was found to be simple and efficient for selective recovery of valuable metals from leachate of spent Li-ion batteries. Pure copper, cobalt and lithium products were obtained, with high elution yields.
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